Derivation
Considering an ideal gas with density
ρ is compressed
PPP
through pressure P then according to ideal gas law:
PV=mMRT,⇒P=mVMRT=ρMRT.
Here
T is the absolute temperature,
R is the universal gas constant equal to
8.314JK⋅mol, M is the molar mass, which is for air equal to
0.029kgmol. It follows from here that the density is given by the formula
ρ=MPRT.
Putting this into the differential relation for
dP gives:
dP=−ρgdh=−MPRTgdh,⇒dPP=−MgRTdh.
We obtain a differential equation describing the gas pressure
P as a function of the altitude
h. Integrating gives the equation:
∫dPP=−∫MgRTdh,⇒lnP=−MgRTh+lnC.
Getting rid of the logarithms, we obtain the so-called
barometric formula
P=Cexp(−MgRTh).
The constant of integration
C can be determined from the initial condition
P(h=0)=P0, where
P0 is the average sea level atmospheric pressure.
Thus, dependency of the barometric pressure on the altitude is given by the formula
P=P0exp(−MgRTh).
Substituting the known constant values (see Figure
2 above), we find that the dependence
P(h) (in kilopascals) is expressed by the formula:
P(h)=101.325exp(−0.02896⋅9.8078.3143⋅288.15h)=101.325exp(−0.00012h)[kPa],
where the height
h above sea level is expressed in meters.
If the pressure is given in millimeters of mercury
(mmHg), the barometric formula is written in the form:
P(h)=760exp(−0.00012h)[mmHg].
In case when the height
h is given in feet, and pressure in inches of mercury
(inHg), this formula is written as
P(h)=29.92exp(−0.00039h)[inHg].
The barometric formula is often used for estimating the air pressure under different conditions, although it gives slightly higher values compared with the real ones.
0 comments:
Post a Comment